PREFACE vii
CONTRIBUTORS ix
PART 1 REACTIVE INTERMEDIATES 1
1. Tetrahedral Intermediates Derived from Carbonyl Compounds,
Pentacoordinate Intermediates Derived from Phosphoryl and Sulfonyl
Compounds, and Concerted Paths Which Avoid Them 3
J.P. Guthrie
2. Silicon-, Germanium-, and Tin-Centered Cations, Radicals,
and Anions 47
V.Y. Lee and A. Sekiguchi
PART 2 METHODS AND APPLICATIONS 121
3. An Introduction to Time-Resolved Resonance Raman Spectroscopy
and Its Application to Reactive Intermediates 123
D.L. Phillips, W.M. Kwok, and C. Ma
4. Time-Resolved Infrared (TRIR) Studies of Organic Reactive
Intermediates 183
J.P. Toscano
5. Studies of the Thermochemical Properties of Reactive
Intermediates by Mass Spectrometric Methods 207
P.G. Wenthold
6. Reactive Intermediates in Combustion 247
J.K. Merle and C.M. Hadad
7. Reactive Intermediates in Crystals: Form and Function 271
L.M. Campos and M.A. Garcia-Garibay
v
vi CONTENTS
8. The Chemical Reactions of DNA Damage and Degradation 333
K.S. Gates
9. Conical Intersection Species as Reactive Intermediates 379
M.J. Bearpark and M.A. Robb
10. Quantum Mechanical Tunneling in Organic Reactive
Intermediates 415
R.S. Sheridan
INDEX 465
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