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2010-11-26 23:27 |
Handbook of Spectroscopic Data: Chemistry - UV,IR,PMR,CNMR and Mass Spectroscopy by: B. Mistry •Publisher: Oxford Book Company •Number Of Pages: 250 •Publication Date: 2009-08-01 •IN-10 / ASIN: 8189473867 •IN-13 / EAN: 9788189473860 "For any organic chemists intending to gain information about a substance, techniques such as ultraviolet, infrared, nuclear magnetic resonance and mass spectra copy are important ones. This book envisages in it much useful spectral data in table and charts. For graduate and post-graduate students and organic research chemist who are not spectro scopists, the book can be a valuable reference for the interpretation of most spectra. In most cases, the organic chemist should be able to interpret a spectrum using these compilations of data without having to search through more detailed texts in the areas." (jacket)
Contents 1. Ultraviolet Spectroscopy 1 2. Infrared Spectroscopy 26 3. Proton Magnetic Resonance Spectroscopy 64 4. Be NMR Spectroscopy 99 5. Mass Spectrometry 128 6. Structural Data Obtainable from Different Spectra 237 Index 240
Index Abietic acid, 7 Absorption frequencies of: alkenes, 45-46 aromatic homocyclic compounds, 47-49 common organic compounds, 27-34 Alcohols: 13C chemical shifts, 111-12 Alkenes and alkynes: 13C chemical shifts, 104-08 Amines: 13C chemical shifts, 114 Aromatic compounds: 13C chemical shifts, 108-11 Aromatic molecules: carbonyl compounds, 13-20 dienes, 7-8 enones, 10-13 polyenes, 8-9 Aromatic systems and derivatives: absorption characteristics, 16-18 Auxochrome substituents, 6 Benzene chromophore, 5-6 Branched chain alkanes, 134 Calculating absorption maxima of: aromatic molecules, 5-13 carbonyl compounds, 3-5 unsaturated compounds, 1-3 Carbonyl compounds, 3-4 Carboxylic acids, ester, chlorides, anhydreds, amides and nitriles: 13C chemical shits, 116-20 Chemical shifts, multiplicities and coupling constants, 86-88 Chemical shifts: alicyclic rings, 72 alkyne protons, 77 fused aromatic rings, 78 heteroaromatic rings, 79 heterocyclic rings, 72-73 methyl, methylene and methane protons, 65-67 Index miscellanceous alkenes, 75-77 monosubstituted benzene rings proton, 77-78 substituent effects, 70-71 two/three functional groups, 68-70 unsaturated and aromatic systems, 73-75 Chromophore substituents, 6 Common fragmentation ions, 225-32 Common fragmentation lost, 233-35 Coupling constants, 122 Cross conjugation, 1 Cutoff wavelength, 19-20 Cyclic diene, 1 Dicarbonyl compounds, 12 Diene absorption: Woodword's and Fieser's rules, 2 Diens and triens: kinds of, 1-2 Different spectra: structural data obtainable, 237-39 Effects of chemical shifts on: alicyclic and heterocyclic rings, 73-80 protons on heteroatoms, 80-81 single functional groups, 65-67 two/three functional groups, 68-71 Enone and dienone absorption rules, 4-5 Enone: solvent correlations, 5 Ergosterol, 8 241 Ethers, acetols and epoxides: 13C chemical shifts, 112-13 Exact masses of isotopes, 129-30 Fragmentation process: alcohols, 137-40 aldehydes, 144-45 alkanes, 132-34 alkenes, 135-36 amides, 151-52 amines, 149-51 aromatic hydrocarbons, 136-37 carboxylic acids and esters, 147-49 ethens, 142-43 ketones, 145-47 phenols and other aromatic alcohols, 140-42 Halides: 13C chemical shifts, 113-14 Heteroannular diene, 2 Heteroatoms, 80-81 Homoannular diene, 2 Incremental shits of aromatic carbon atoms of monosaturat.::d benzenes, 108-10 Incremental substituents effects, 102 Infrared absorption and structure of organic compounds: correlations, 34-35 Ketones and aldehydes: 13C chemical shifts, 115-16 242 Linear and branched alkanes: 13C chemical shifts, 94-104 Linear conjugation, 1 Mass spectroscopy, 128-235 Mass spectrum, 128 McLafferty rearrangements, 135, 136,144,147 Molecular ion, 128-29 Mulling oils, 58 Multiplicities, 13C chemical shifts and couplings of common NMR solvents, 123-24 NMR spectroscopy, 90-127 NMR table of correlations of chemical shifts of protons, 88-93 Ortho and meta substitution, 15 Oximes: 13C chemical shifts, 120 Para substitution, 14 Parameters of 13C chemical shifts, 100 Polycyclic aromatic compounds: absorption characteristics, 15 Polyenes,3 Proton magnetic resonance spectroscopy, 64-93 Proton spin coupling constants, 81-85 Protons on heteroatoms, 80-81 Index Recognition of molecular ion peak, 131-32 Relative isotopic abundance of common elements, 130 Retro-Diels-Alder reaction, 135 Scott's rule for "-max of ET band, 6-7 Semicyclic diene, 1-2 Shielding constants, 68-69 Solvents and mulling oils: infrared tranission characteristics, 57-58 Some CJCH) values, 120-21 Some eJCH) values, 121-22 Spin coupling, 120-22 Stretching frequencies of: carbonyl compounds, 49-53 cyclic and acyclic systems, 47 Substituent constants, 74-75 Substituent effects on chemical shifts, 70-71 Table of 13C correlation for chemical classes, 124-27 Thiols, sulfides and disulfides: 13Cchemicalshifts, 114-15 Trans f3-carotene, 8-9 Translycopene, 9 Ultraviolet spectroscopy, 1-20 Variations of carbonyl stretching band,53-54 Vibration modes of amines and amino acids, 55-56
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